Magnesia Zirconia Bricks

Magnesia Zirconia Bricks
Details:
Magnesia zirconia bricks are manufactured using high-purity fused magnesia (≥97% MgO) and stabilized zirconia (typically CaO or Y₂O₃ stabilized), carefully proportioned to optimize both corrosion resistance and thermal shock performance. The unique microstructure features periclase (MgO) grains bonded by a zirconia-rich matrix, creating a refractory product that combines the best properties of both oxide systems. This brick grade is particularly valued for its self-healing characteristics, where the zirconia phase undergoes martensitic transformation under stress, effectively arresting crack propagation and extending service life.
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Description
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Magnesia zirconia bricks provide an eco-friendly, high-performance alternative with 2-3x longer service life in critical zones like ladle slag lines, AOD converters, and cement rotary kiln transition zones. Their low thermal conductivity combined with excellent volume stability makes them ideal for energy-intensive processes where thermal efficiency and lining longevity are paramount.

These bricks are characterized by their high content of magnesium oxide (MgO) and zirconium oxide (ZrO₂), typically ranging from 70% to 90% MgO and 8% to 12% ZrO₂. The bricks have a bulk density greater than 3.05 g/cm³ and a cold crushing strength of over 50 MPa. They also exhibit excellent thermal stability, with a refractoriness under load of up to 1650°C. The uniform phase structure of these bricks ensures that the periclase and calcium zirconate are directly combined, making the space between the crystal grains resistant to erosion by liquid phases or slag.

 

Product Parameters

 

Parameter Unit Value
Chemical Composition    
Magnesium Oxide (MgO) % ≥70 - 97
Zirconium Oxide (ZrO₂) % ≥6.5 - 13
Silicon Dioxide (SiO₂) % ≤1.5 - 9.5
Calcium Oxide (CaO) % ≤1.5 - 6.0
Physical Properties
Apparent Porosity (A.P) % ≤16 - 18
Bulk Density g/cm³ >3.05
Cold Crushing Strength MPa >50
Refractoriness Under Load (RUL) °C ≥1650
Packaging Type   Wooden crates or pallets
Applications   Glass kilns, cement kilns, steelmaking electric furnaces, non-ferrous metal smelting furnaces

 

Product Usage:

Magnesia zirconia bricks are widely used in industries that require materials to withstand high temperatures and corrosive environments. They are commonly used in the regenerators of glass kilns, where their thermal shock resistance and high-temperature performance make them an ideal choice. Additionally, these bricks are used in cement kilns, steelmaking electric furnaces, and non-ferrous metal smelting furnaces. Their ability to resist alkali metals, oxides, and sulfides makes them suitable for applications in the glass industry, where they can significantly improve the efficiency and longevity of kiln components.

 

Product Advantages

Superior Slag Resistance

Demonstrates 5-8x better corrosion resistance against basic slags compared to standard magnesia bricks, The zirconia component forms a protective barrier against lime-rich slags.

Thermal Shock Stability

Withstands 50+ rapid cooling cycles without spalling thanks to zirconia's unique transformation toughening mechanism

High-Temperature Strength

Maintains cold crushing strength >50 MPa even after prolonged exposure to operating temperatures up to 1750°C (3182°F), preventing structural collapse in aggressive environments.

Environmental Compliance

Completely chrome-free, addressing growing regulatory restrictions on hexavalent chromium while delivering comparable or superior performance to magnesia-chrome bricks.

Thermal Efficiency

Lower thermal conductivity than conventional basic bricks (1.8-2.2 W/m·K at 1000°C), reducing heat loss through vessel walls and improving energy efficiency.

Oxidation Resistance


These bricks perform reliably in oxidizing atmospheres without degradation.

 

Product technology:

 

The production of premium magnesia zirconia bricks follows a meticulously controlled process that ensures optimal phase distribution and microstructure development. We begin with high-purity raw materials – 97-98% fused magnesia (with controlled CaO/SiO₂ ratios) and 94-96% stabilized zirconia (typically CaO or Y₂O₃ stabilized to prevent phase transformations during cooling). These materials are wet-milled to precise particle size distributions before blending with temporary organic binders.

mgo zironia brick process

Key steps include:

Precision Mixing: Computer-controlled batch mixing ensures homogeneous distribution of zirconia within the magnesia matrix.

High-Pressure Forming: Hydraulic pressing at 150-200 MPa achieves uniform density (>3.0 g/cm³) with minimal porosity.

Drying: Controlled humidity drying cycles prevent cracking in green products.

High-Temperature Firing: Tunnel kiln firing at 1650-1750°C develops the critical ceramic bond between magnesia and zirconia phases.

Why Choose Us?

 

1

High-Quality Materials:

We use only high-purity magnesia to ensure superior performance and durability.

2

Advanced Manufacturing:

State-of-the-art technology and rigorous quality control guarantee consistent quality.

3

Custom Solutions:

Tailored products to meet specific application requirements.

4

Global Expertise:

Trusted by clients worldwide for reliable and innovative refractory solutions.

5

Competitive Pricing:

Cost-effective solutions without compromising quality.

6

24/7 After-Sales Support:

Our team is always available to provide technical assistance and troubleshooting.

 

Packing

  • Magnesia zirconia bricks are typically packaged in wooden crates or pallets to ensure safe transportation and storage. Each brick is carefully wrapped to prevent damage during transit. The packaging is designed to protect the bricks from moisture and physical impact, maintaining their integrity until they reach the end-user. Proper packaging also facilitates easy handling and storage on construction sites or in industrial facilities.
magnesia brick packing

 

FAQ

 

Q: What is the primary advantage of using magnesia zircon bricks over other refractory materials?

A: Magnesia zirconia refractory bricks offer superior resistance to thermal shock and chemical attack. Their high density and low porosity make them ideal for applications where other materials may fail.

Q: How do magnesia zirconia firebricks contribute to energy efficiency in industrial processes?

A: The low porosity of magnesia zirconia refractory bricks reduces heat loss, improving thermal efficiency. This can lead to significant energy savings and reduced operational costs.

Q:Can magnesia zirconia bricks be customized for specific applications?

A: Yes, our company offers customization options to meet the unique requirements of different industrial applications. We can adjust the chemical composition and physical properties of the bricks to optimize their performance

Q: Can these bricks be used in reducing atmospheres?

A: While optimized for oxidizing/neutral conditions, our zirconia-doped magnesia-carbon line may be preferable for strongly reducing environments.

 

 

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